(E)-2-[2-(Hydroxymethyl)phenyliminomethyl]-6-methylphenol
نویسندگان
چکیده
منابع مشابه
2-tert-Butyl-6-[(4-chloro-2-nitrophenyl)diazenyl]-4-methylphenol
In the title compound, C(17)H(18)ClN(3)O(3), the dihedral angle between the planes of the two benzene rings is 1.03 (7)°. The overall conformation of the mol-ecule is influenced, in part, by electron delocalization and by an intra-molecular bifurcated O-H⋯(O,N) hydrogen bonds. The O atoms of the nitro group, one of which serves as an H bond acceptor, are disordered over two sets of sites with r...
متن کامل2-[(E)-(2-Chlorophenyl)iminomethyl]-6-methylphenol
The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl-salicyl-aldehyde, crystallizes in the phenol-imine tautomeric form with an E conformation for the imine functionality. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°. The hy-droxy H atom is involved in a strong intra-molecular O-H⋯N hydrogen bond, generating an S(6) ring.
متن کامل(E)-2-[(2-Ethylphenyl)iminiomethyl]-6-hydroxyphenolate
The mol-ecule of the title compound, C(15)H(15)NO(2), crystallizes in a zwitterionic form, and displays an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 5.59 (6)°. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, pairs of mol-ecules are linked into centrosymmetric R(2) (2)(10) dimers by pairs of O-H⋯O hydro...
متن کامل(E)-2-[(2-Hydroxyethyl)iminiomethyl]-6-methoxyphenolate
The title Schiff base compound, C(10)H(13)NO(3), obtained by the reaction of 2-hydr-oxy-3-methoxy-benzaldehyde and 2-amino-ethanol in methanol solution, crystallizes in a zwitterionic form, in which the mol-ecule adopts a trans configuration about the central C=N bond. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal structure, mol-ecules are linked into chains by inter-molecular O...
متن کامل(E)-2-[(2-Ethylphenyl)iminomethyl]-6-methoxyphenol
The mol-ecule of the title compound, C(16)H(17)NO(2), adopts the phenol-imine tautomeric form with a strong intra-molecular O-H⋯N hydrogen bond and an E conformation with respect to the azomethine C=N bond. The dihedral angle between the aromatic rings is 21.23 (9)°. The ethyl group is disordered over two orientations with occupancies of 0.598 (6) and 0.402 (6). In the crystal, the mol-ecules a...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536807032266